Constitution and Dynamics of “Waterproof”

Becoming behavior of rare-earth ions (REI) in crowded environments is crucial for a couple of nano- and bio-technological applications. Advancement of REI photoluminescence (PL) appearing in small compartments inside a silica hydrogel, mimic to a soft matter bio-environment, has been studied and explained just a solvation model. The model revealed the origin of high PL efficiency like a formation of REI complexes, between bile salt (DOC) molecules. More acceptable study of these REI/DOC complexes more than one item water solution and those enclosed ?nside the hydrogel revealed a strong correlation approximately an up to 5x-longer lifetime of REIs and appearance of the DOC ordered movement, further confirmed by dynamics concerning REI solvation shells, REI durchmischung experiments and morphological characterization concerning microstructure of the hydrogel.

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